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Equation (161) provides semiquantitative representations of thermodynamic and transport properties for nonpolar substances of relatively simple molecular structure In Eq (161), the r-l2 term is supposed to represent bimolecular repulsions, and the r p 6term bimolecular attractions Although the attraction term has significant theoretical justification, the r-l2 dependence for repulsions is chosen primarily for mathematical convenience Table 161 shows some values of the dimensionless potential energy U / r as a function of the dimensionless separation r l o , as implied by Eq (161) Clearly, the effects of intermolecular forces are significant only over a modest range of separations Although they operate over an infinite range (U and F together approach zero only in the limit as r + oo), both U and F for neutral molecular pairs are numerically negligible for separations greater than about 10 molecular diameters

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By game time, he knew, the game was out of his hands and in the hands of his players Of the 70 or so plays in a typical game, Lombardi sent in less than a dozen, and even then, his quarterback had the right to change the play with an audible at the line of scrimmage It would be an exaggeration to say that the coach was now simply the cheerleader But in a real sense, the coach was now fan number one of the team he had trained and equipped My mother had an interesting perspective on this process On Monday, Tuesday, and Wednesday, she used to say half jokingly, we don t talk, because on Wednesday, he has to go out there and convince himself, the coaches, and the players that they can win On Thursday, we say hello On Friday, he is civil At the beginning of the week, in other words, the weight of the world was on his shoulders By the end of the week, he had put that weight squarely on the shoulders of the players He had made them accountable

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The origins of intermolecular forces stem from the essential concept that a molecule is a distribution of charges: a collection of positively charged nuclei, surrounded by a cloud of negatively charged electrons Intermolecular repulsions at sufficiently small separations therefore result from the overlap of electron clouds of interacting molecules, giving rise to a Coulombic repulsion At still smaller separations the positively charged nuclei "see" each other, again promoting repulsion The origins of intermolecular attractions are less obvious, and several mechanisms can contribute First, consider the electrostatic interaction of two rigid charge distributions A and B By Coulomb's law, the electrostatic potential energy of interaction U(e1) is:

a compilation of expressions for U see G C Maitland, M Rigby, E B Smith, and W A Wakeham, Intermolecular Forces: Their Origin and Determination, app 1, Clarendon Press, Oxford, 1981

a Solution (5) barium chloride will give a precipitate The formula of the precipitate is BaCrO4 You get 1 point for picking the correct solution, and 1 point for the correct formula for the precipitate b Solution (3) sodium carbonate is the most basic Since the carbonate ion is the conjugate base of a weak acid, it will undergo significant hydrolysis to produce a basic solution You get 1 point for picking the correct solution, and 1 point for the correct explanation c Solution (2) methyl alcohol will show the least boiling point elevation Methyl alcohol is the only nonelectrolyte You get 1 point for picking the correct solution, and 1 point for the correct formula for the explanation d Solution (4) ammonium chromate is yellow You get 1 point for picking the correct solution e Solution (2) methyl alcohol is the only solution that will not form a precipitate with barium chloride You get 1 point for picking the correct solution

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