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As noted in Sec 33, an ideal gas is characterized by the absence of molecular interactions; nevertheless, it still possesses internal energy This energy is associated with the individual molecules, and results from their motion Real gases and other fluids are comprised of molecules that have not only the energy of individual molecules, but also energy that is shared among them because of intermolecular forces This intermolecularpotential energy is associated with collections of molecules, and is the form of energy that reflects the existence of such forces Well established is the fact that two molecules attract each other when they are far apart and repel one another when close together Electromagnetic in origin, intermolecular forces represent interactions among the charge distributions of neighboring molecules

Finally, after telling his players what he expected of them and giving them the tools to do it, Lombardi got out of their way To some extent, the instilling of accountability was a cumulative and continuing process (Veterans were expected to understand their responsibilities on the first day of training camp; first-year players were cut a little slack until they were brought up to speed) But there was another dynamic at work as well, a weekly transfer of responsibility from coach to team At the beginning of the week, Lombardi had to break down what had happened on Sunday both the good and the bad and point it out to the players But by midweek, he had to be accentuating the positive and explaining how the Packers were going to win their next game As I explained in 6, this was the confidence-building phase

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Figure 161 The intermolecular potential energy U for a pair of structureless, neutral molecules (Not to scale)

You have 20 minutes to answer the following questions You may not use a calculator You may use the tables in the back of the book Five beakers are placed in a row on a countertop Each beaker is half filled with a 020 M aqueous solution The solutes, in order, are: (1) potassium sulfate, (2) methyl alcohol, (3) sodium carbonate, (4) ammonium chromate, and (5) barium chloride The solutions are all at 25 C Answer the following questions with respect to the five solutions listed above a Which solution will form a precipitate when ammonium chromate is added to it Give the formula of the precipitate b Which solution is the most basic Explain c Which solution will exhibit the lowest boiling-point elevation Explain d Which solution is colored e Which of the other solutions will not react with solution (5), barium chloride

Figure 161 is a sketch of the intermolecular potential energy U for an isolated pair of spherically symmetric neutral molecules, for which M depends only on the distance between the molecular centers, ie, on the intermolecular separation r (More generally, U is also a function of the relative orientations of the two molecules) The intermolecular force F is proportional to the r-derivative of U :

LOMBARDI RULE #3

By convention, a positive F represents an intermolecular repulsion, and a negative F an intermolecular attraction Hence (Fig 161) molecules repel each other at small separations, and attract each other at modest-to-large separations An algebraic expression for the pair-potential function 24 is one of the tools of the trade of the molecular scientist or engineer The methods of statistical mechanics provide for its relation to both thermodynamic and transport properties Shown in Fig 161 are specific values for U and r that may appear as species-dependent parameters in a pair-potential function

The hard-core diameter d is a measure of the center-to-center separation for which U, and hence F, becomes infinite It is not subject to precise determination, but plays the role of a modeling parameter in some expressions for U The collision diameter o is defined as the separation for which U = 0 The equilibrium separation ro is the separation for which U attains its minimum value of - E At r = ro, the net intermolecular force is zero Quantity E is called the well depth For a particular class of chemical species (eg, noble gases, or cyclic alkanes), each of these special quantities increases with increasing molecular size Typical J Commonly, ranges of values for o and E are 0 x 3 to 8 x 10-lo m and E x 01 to 10 x ro is about 10 to 15% greater than o Scores of expressions have been proposed for U' All are essentially empirical, although their functional forms often have some basis in theory The most widely used is the LennardJones (LJ) 12/6pair-potential function:

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