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The second Lombardi tactic for building accountability was giving the players all the tools they needed to do their jobs He recognized that he couldn t ask people to take accountability for their work if they didn t have everything they needed to do their work Perhaps this sounds self-evident But look back over the places where you ve worked, and ask yourself whether you always had the right tools Did you ever suffer with an uncomfortable chair, a dumb computer, outmoded software, bad market information, a truck with mechanical ailments, inadequate lighting, or any of the thousand-and-one other problems that plague the typical workplace The Packers didn t have these problems or their football equivalents They had all the tools they needed They were prepared mentally and physically for every game They were almost never surprised by what the opposing team did In the fourth quarter, they almost always found themselves in better physical condition than the opposition (Their bodies were one of their most important tools) At my father s insistence, the Packers did everything first class: facilities, equipment, travel, and lodging Lombardi understood that each of these things, considered separately, was more or less trivial Taken together, though, they created an atmosphere of professionalism They instilled the clear sense in the minds of the players that everything possible was being done to ensure their success

You have 20 minutes to answer the following questions You may not use a calculator You may use the tables at the back of the book Five beakers each containing 1000 mL of an aqueous solution are placed on a lab bench The solutions are all at 25 C Solution 1 contains 020 M KNO3 Solution 2 contains 010 M BaCl2 Solution 3 contains 015 M C2H4(OH)2 Solution 4 contains 020 M (NH4)2SO4 Solution 5 contains 025 M KMnO4 a One of the solutions could oxidize two of the other solutions Which solution is it Which solutions could it oxidize b Which solution has the lowest pH Explain c Which pair of solutions would give a precipitate if they are mixed What is the formula for this precipitate d Which solution would be the poorest conductor of electricity Explain e Rank the solutions in order of increasing boiling point Explain

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Classical thermodynamics is a deductive science, in which the general features of macroscopicsystem behavior follow from a few laws and postulates However, the practical application of thermodynamics requires values for the properties of individual chemical species and their mixtures These may be presented either as numerical data (eg, the steam tables for water) or as correlating equations (eg, a P VT equation of state and expressions for the temperature dependence of ideal-gas heat capacities) The usual source of property values is experiment For example, the ideal-gas equation of state evolved as a statement of observed volumetricbehavior of gases at low pressures Similarly, the rule of thumb that C p x 29 J mol-' K-' for diatomic gases at normal temperatures is based on experimental observation However, macroscopic experiments provide no insight into why substances exhibit their observed property values The basis for insight is a microscopic view of matter A central dogma of modern physics is that matter is particulateThe quest for the ultimate elementary particles is still in progress, but for engineering purposes we may adopt the following picture: ordinary matter consists of molecules; molecules consist of atoms; and atoms consist of a positively charged nucleus (comprising neutrons and protons), surrounded by negatively charged electrons Atoms and molecules with equal numbers of electrons and protons have no net charge and are neutral

Molecules are small and light: typical linear dimensions are 1 0 ~ to ~ ' lop8 m, and typical masses are to kg Hence the number of molecules in a macroscopic system is enormous For example, one mole of matter contains 6022 x molecules (Avogadro's number) Because of these features- smallness, lightness, and numerical abundance- the proper description of behavior at the molecular level and its extrapolation to a macroscopic scale require the special methods of quantum mechanics and statistical mechanics We pursue neither of these topics here Instead, we present material useful for relating molecular concepts to observed thermodynamic properties

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